The combustion chamber pressure and temperature are the main driving forces behind system design.
The SPARCC 3.0 system is designed to use a custom HTPB / Ammonium Perchlorate composite propellant.
I took many different approaches to try and analytically determine the chamber pressure:
- Organic Chemistry Approach:
Using the chemical structures of the HTPB hydrocarbon and Ammonium Perchlorate, attempted to determine the bonding enthalpy. Using this and the specific heats at constant pressure (Cp), the final temperature of the combustion was found to be 15,655.7 K, which is definitely incorrect.
The main issue with this method is that I used constant pressure instead of constant volume, as the volume of the combustion chamber is set to be constant (150 cc).
- NASA's CEA Approach:
Using NASA's Chemical Equilibrium with Applications (CEA) to determine the equilibrium state of the combustion products, including their relative compositions and temperature.
This resulted in a chamber pressure of 127 atm and 3,297 K, which also seems quite high.
The main issue with this approach is that it seems the software is directed for constant fluid flow engines, whereas SPARCC 3.0 operates in a pulse mode, which means that the pressure values will inherently be incorrect.
- Propulsion Textbook Approach:
Using rockets and compressible flow equations, the chamber temperature for a set area ratio was found assuming ideal expansion.
This resulted in a chamber temperature of 625 K, and the chamber pressure was found to be 5.13 atm, which seemed to be much more realistic than the two methods before.
These values were much more realistic, and were deemed close enough by the team to move forward with system design.
- Experimental Approach:
After the above analytical approaches, the team moved forward with attempting to find these values experimentally.
The team built a scaled-down test chamber using galvanized steel pipe and ignited a 1/3 scale propellant pellet inside.
A thermometer probe was placed on the exit of the chamber in order to measure the temperature right at the exit of the chamber.
After three trials, on average the chamber temperature was found to be 1,145 K, and via the ideal gas law the pressure was found to be 9.4 atm.
These values will be compared against through further thrust tests.